"Tsuji-Trost reaction" meaning in All languages combined

See Tsuji-Trost reaction on Wiktionary

Noun [English]

Forms: Tsuji-Trost reactions [plural]
Etymology: Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands. Head templates: {{en-noun|head=Tsuji-Trost reaction}} Tsuji-Trost reaction (plural Tsuji-Trost reactions)
  1. (chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product. Wikipedia link: Tsuji-Trost reaction Categories (topical): Chemistry
    Sense id: en-Tsuji-Trost_reaction-en-noun-31aLYa5~ Categories (other): English entries with incorrect language header, Pages with 1 entry, Pages with entries Topics: chemistry, natural-sciences, physical-sciences

Inflected forms

{
  "etymology_text": "Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.",
  "forms": [
    {
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      "tags": [
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  "head_templates": [
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  "lang_code": "en",
  "pos": "noun",
  "senses": [
    {
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        {
          "kind": "other",
          "name": "English entries with incorrect language header",
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          "source": "w"
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        },
        {
          "kind": "topical",
          "langcode": "en",
          "name": "Chemistry",
          "orig": "en:Chemistry",
          "parents": [
            "Sciences",
            "All topics",
            "Fundamental"
          ],
          "source": "w"
        }
      ],
      "glosses": [
        "A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "id": "en-Tsuji-Trost_reaction-en-noun-31aLYa5~",
      "links": [
        [
          "chemistry",
          "chemistry"
        ],
        [
          "palladium",
          "palladium"
        ],
        [
          "substitution reaction",
          "substitution reaction"
        ],
        [
          "substrate",
          "substrate"
        ],
        [
          "leaving group",
          "leaving group"
        ],
        [
          "allylic",
          "allylic"
        ]
      ],
      "raw_glosses": [
        "(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "topics": [
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        "natural-sciences",
        "physical-sciences"
      ],
      "wikipedia": [
        "Tsuji-Trost reaction"
      ]
    }
  ],
  "word": "Tsuji-Trost reaction"
}
{
  "etymology_text": "Pioneered by Jiro Tsuji in 1965 and later adapted by Barry Trost in 1973 with the introduction of phosphine ligands.",
  "forms": [
    {
      "form": "Tsuji-Trost reactions",
      "tags": [
        "plural"
      ]
    }
  ],
  "head_templates": [
    {
      "args": {
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      },
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    }
  ],
  "lang": "English",
  "lang_code": "en",
  "pos": "noun",
  "senses": [
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        "English entries with incorrect language header",
        "English eponyms",
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        "English multiword terms",
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        "Pages with entries",
        "en:Chemistry"
      ],
      "glosses": [
        "A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "links": [
        [
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        [
          "palladium",
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        [
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        ],
        [
          "substrate",
          "substrate"
        ],
        [
          "leaving group",
          "leaving group"
        ],
        [
          "allylic",
          "allylic"
        ]
      ],
      "raw_glosses": [
        "(chemistry) A palladium-catalysed substitution reaction involving a substrate that contains a leaving group in an allylic position. The palladium catalyst first coordinates with the allyl group and then undergoes oxidative addition, forming the π-allyl complex. This allyl complex can then be attacked by a nucleophile, resulting in the substituted product."
      ],
      "topics": [
        "chemistry",
        "natural-sciences",
        "physical-sciences"
      ],
      "wikipedia": [
        "Tsuji-Trost reaction"
      ]
    }
  ],
  "word": "Tsuji-Trost reaction"
}

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This page is a part of the kaikki.org machine-readable All languages combined dictionary. This dictionary is based on structured data extracted on 2024-12-03 from the enwiktionary dump dated 2024-11-21 using wiktextract (94ba7e1 and 5dea2a6). The data shown on this site has been post-processed and various details (e.g., extra categories) removed, some information disambiguated, and additional data merged from other sources. See the raw data download page for the unprocessed wiktextract data.

If you use this data in academic research, please cite Tatu Ylonen: Wiktextract: Wiktionary as Machine-Readable Structured Data, Proceedings of the 13th Conference on Language Resources and Evaluation (LREC), pp. 1317-1325, Marseille, 20-25 June 2022. Linking to the relevant page(s) under https://kaikki.org would also be greatly appreciated.